trans-Diiodidobis(2-phenylpyridine-κN)palladium(II)
نویسنده
چکیده
In the title complex, [PdI(2)(C(11)H(9)N)(2)], the Pd(II) ion has a distorted trans-I(2)N(2) square-planar coordination geometry defined by two N atoms from two 2-phenyl-pyridine ligands and two I(-) anions. The 2-phenyl-pyridine ligands are not planar, the dihedral angles between the pyridine and benzene rings being 50.1 (2) and 45.7 (2)°. An inter-molecular π-π inter-action between the six-membered rings is present, the ring centroid-centroid distance being 3.898 (4) Å.
منابع مشابه
trans-Dichloridobis(4-phenylpyridine-κN)palladium(II)
The asymmetric unit of the title complex, [PdCl(2)(C(11)H(9)N)(2)], contains one half of a neutral Pd(II) complex, with the complete mol-ecule generated by the application of a twofold rotation axis; the N-Pd-N atoms lie on the axis. The Pd(II) ion has a trans-Cl(2)N(2) square-planar coordination geometry defined by two N atoms from two 4-phenyl-pyridine ligands and two Cl(-) anions. In the ref...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012